Isotopes of ununennium

Template:SHORTDESC: Ununennium (₁₁₉Uue) has not yet been synthesised, so there is no experimental data and a standard atomic weight cannot be given. Like all synthetic elements, it would have no stable isotopes.

List of isotopes

No isotopes of ununennium are known.

Nucleosynthesis

Target-projectile combinations leading to Z = 119 compound nuclei

The below table contains various combinations of targets and projectiles that could be used to form compound nuclei with Z = 119.

Target	Projectile	CN	Attempt result
208Pb	87Rb	295Uue	Template:Unk
209Bi	86Kr	295Uue	Template:Unk
238U	59Co	297Uue	Template:Unk
237Np	58Fe	295Uue	Template:Unk
244Pu	55Mn	299Uue	Template:Unk
243Am	54Cr	297Uue	Template:Unk
248Cm	51V	299Uue	Reaction being attempted
250Cm	51V	301Uue	Template:Unk
249Bk	50Ti	299Uue	Failure to date
249Cf	45Sc	294Uue	Template:Unk
254Es	48Ca	302Uue	Failure to date

Cold fusion

Following the claimed synthesis of ²⁹³Og in 1999 at the Lawrence Berkeley National Laboratory from ²⁰⁸Pb and ⁸⁶Kr, the analogous reactions ²⁰⁹Bi + ⁸⁶Kr and ²⁰⁸Pb + ⁸⁷Rb were proposed for the synthesis of element 119 and its then-unknown alpha decay daughters, elements 117, 115, and 113. The retraction of these results in 2001 and more recent calculations on the cross sections for "cold" fusion reactions cast doubt on this possibility; for example, a maximum yield of 2 fb is predicted for the production of ²⁹⁴Uue in the former reaction. Radioactive ion beams may provide an alternative method utilizing a lead or bismuth target, and may enable the production of more neutron-rich isotopes should they become available at required intensities.

Hot fusion

²⁴³Am(⁵⁴Cr,xn)^297−xUue

There are indications that the team at the Joint Institute for Nuclear Research (JINR) in Russia plans to try this reaction in the future. The product of the 3n channel would be ²⁹⁴Uue; its expected granddaughter ²⁸⁶Mc was synthesised in a preparatory experiment at the JINR in 2021, using the reaction ²⁴³Am(⁴⁸Ca,5n)²⁸⁶Mc.

The team at the Heavy Ion Research Facility in Lanzhou (HIRFL), which is operated by the Institute of Modern Physics (IMP) of the Chinese Academy of Sciences, also plans to try the ²⁴³Am+⁵⁴Cr reaction.

²⁴⁸Cm(⁵¹V,xn)^299−xUue

The team at RIKEN in Wakō, Japan began bombarding curium-248 targets with a vanadium-51 beam in January 2018 to search for element 119. Curium was chosen as a target, rather than heavier berkelium or californium, as these heavier targets are difficult to prepare. The reduced asymmetry of the reaction is expected to approximately halve the cross section, requiring a sensitivity "on the order of at least 30 fb". The ²⁴⁸Cm targets were provided by Oak Ridge National Laboratory. RIKEN developed a high-intensity vanadium beam. The experiment began at a cyclotron while RIKEN upgraded its linear accelerators; the upgrade was completed in 2020. Bombardment may be continued with both machines until the first event is observed; the experiment is currently running intermittently for at least 100 days per year. The RIKEN team's efforts are being financed by the Emperor of Japan.

Template:Nuclide + Template:Nuclide → Template:Nuclide* → no atoms yet

The produced isotopes of ununennium are expected to undergo two alpha decays to known isotopes of moscovium (²⁸⁸Mc and ²⁸⁷Mc respectively), which would anchor them to a known sequence of five further alpha decays and corroborate their production. In 2022, the optimal reaction energy for synthesis of ununennium in this reaction was experimentally estimated as 234.8±1.8 MeV at RIKEN. The cross section is probably below 10 fb.

As of September 2023, the team at RIKEN had run the ²⁴⁸Cm+⁵¹V reaction for 462 days. A report by the RIKEN Nishina Center Advisory Committee noted that this reaction was chosen because of the availability of the target and projectile materials, despite predictions favoring the ²⁴⁹Bk+⁵⁰Ti reaction, owing to the ⁵⁰Ti projectile being closer to doubly magic ⁴⁸Ca and having an even atomic number (22); reactions with even-Z projectiles have generally been shown to have greater cross-sections. The report recommended that if the 5 fb cross-section limit is reached without any events observed, then the team should "evaluate and eventually reconsider the experimental strategy before taking additional beam time." As of August 2024, the team at RIKEN was still running this reaction "24/7".

²⁴⁹Bk(⁵⁰Ti,xn)^299−xUue

From April to September 2012, an attempt to synthesize the isotopes ²⁹⁵Uue and ²⁹⁶Uue was made by bombarding a target of berkelium-249 with titanium-50 at the GSI Helmholtz Centre for Heavy Ion Research in Darmstadt, Germany. This reaction between ²⁴⁹Bk and ⁵⁰Ti was predicted to be the most favorable practical reaction for formation of ununennium, as it is rather asymmetrical, though also somewhat cold. (The reaction between ²⁵⁴Es and ⁴⁸Ca would be superior, but preparing milligram quantities of ²⁵⁴Es for a target is difficult.) Moreover, as berkelium-249 decays to californium-249 (the next element) with a short half-life of 327 days, this allowed elements 119 and 120 to be searched for simultaneously. Nevertheless, the necessary change from the "silver bullet" ⁴⁸Ca to ⁵⁰Ti divides the expected yield of ununennium by about twenty, as the yield is strongly dependent on the asymmetry of the fusion reaction. Due to the predicted short half-lives, the GSI team used new "fast" electronics capable of registering decay events within microseconds.

Template:Nuclide + Template:Nuclide → Template:Nuclide* → no atoms

Template:Nuclide + Template:Nuclide → Template:Nuclide* → no atoms

Neither element 119 nor element 120 was observed. This implied a limiting cross-section of 65 fb for producing element 119 in these reactions, and 200 fb for element 120. The predicted actual cross section for producing element 119 in this reaction is around 40 fb, which is at the limits of current technology. (The record lowest cross section of an experimentally successful reaction is 30 fb for the reaction between ²⁰⁹Bi and ⁷⁰Zn producing nihonium.) The experiment was originally planned to continue to November 2012, but was stopped early to make use of the ²⁴⁹Bk target to confirm the synthesis of tennessine (thus changing the projectiles to ⁴⁸Ca).

The team at the Joint Institute for Nuclear Research in Dubna, Russia, planned to attempt this reaction.

²⁵⁴Es(⁴⁸Ca,xn)^302−xUue

The synthesis of ununennium was first attempted in 1985 by bombarding a sub-microgram target of einsteinium-254 with calcium-48 ions at the superHILAC accelerator at Berkeley, California:

Template:Nuclide + Template:Nuclide → Template:Nuclide* → no atoms

No atoms were identified, leading to a limiting cross section of 300 nb. Later calculations suggest that the cross section of the 3n reaction (which would result in ²⁹⁹Uue and three neutrons as products) would actually be six hundred thousand times lower than this upper bound, at 0.5 pb. Tens of milligrams of einsteinium, an amount that cannot presently be produced, would be needed for this reaction to have a reasonable chance of succeeding.