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Manganese, 25MnA rough fragment of lustrous silvery metal Pure manganese cube and oxidized manganese chips |
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Pronunciation | (MANG-gə-neez) |
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Appearance | silvery metallic |
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Atomic number (Z) | 25 |
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Group | group 7 |
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Period | period 4 |
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Block | d-block |
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Electron configuration | [Ar] 3d5 4s2 |
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Electrons per shell | 2, 8, 13, 2 |
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Phase at STP | solid |
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Melting point | 1519 K (1246 °C, 2275 °F) |
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Boiling point | 2334 K (2061 °C, 3742 °F) |
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Density (at 20° C) | 7.476 g/cm3 [3] |
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when liquid (at m.p.) | 5.95 g/cm3 |
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Heat of fusion | 12.91 kJ/mol |
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Heat of vaporization | 221 kJ/mol |
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Molar heat capacity | 26.32 J/(mol·K) |
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Vapor pressure
P (Pa)
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1
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10
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100
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1 k
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10 k
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100 k
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at T (K)
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1228
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1347
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1493
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1691
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1955
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2333
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Oxidation states | common: +2, +4, +7
−3,[4] −2,[5][4] −1,[4] 0,[4] +1,[4] +3,[4] +5,[4] +6[4] |
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Electronegativity | Pauling scale: 1.55 |
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Ionization energies | - 1st: 717.3 kJ/mol
- 2nd: 1509.0 kJ/mol
- 3rd: 3248 kJ/mol
- (more)
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Atomic radius | empirical: 127 pm |
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Covalent radius | Low spin: 139±5 pm High spin: 161±8 pm |
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Color lines in a spectral rangeSpectral lines of manganese |
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Natural occurrence | primordial |
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Crystal structure | α-Mn: body-centered cubic (bcc) (cI58) |
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Lattice constant | a = 891.16 pm (at 20 °C)[3] |
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Thermal expansion | 23.61×10−6/K (at 20 °C)[3] |
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Thermal conductivity | 7.81 W/(m⋅K) |
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Electrical resistivity | 1.44 µΩ⋅m (at 20 °C) |
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Magnetic ordering | paramagnetic |
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Molar magnetic susceptibility | (α) +529.0×10−6 cm3/mol (293 K)[6] |
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Young's modulus | 198 GPa |
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Bulk modulus | 120 GPa |
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Speed of sound thin rod | 5150 m/s (at 20 °C) |
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Mohs hardness | 6.0 |
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Brinell hardness | 196 MPa |
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CAS Number | 7439-96-5 |
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Discovery | Carl Wilhelm Scheele (1774) |
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First isolation | Johann Gottlieb Gahn (1774) |
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File:Symbol category class.svg Category: Manganese | references |
child table, as reused in {IB-Mn} |
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References
These references will appear in the article, but this list appears only on this page.
- ↑ Lua error in Module:Citation/CS1/Configuration at line 2088: attempt to index field '?' (a nil value).
- ↑ Lua error in Module:Citation/CS1/Configuration at line 2088: attempt to index field '?' (a nil value).
- ↑ 3.0 3.1 3.2 Lua error in Module:Citation/CS1/Configuration at line 2088: attempt to index field '?' (a nil value).
- ↑ 4.0 4.1 4.2 4.3 4.4 4.5 4.6 4.7 Lua error in Module:Citation/CS1/Configuration at line 2088: attempt to index field '?' (a nil value).
- ↑ Mn(–2) is known in Mn(cod)2−2; see Lua error in Module:Citation/CS1/Configuration at line 2088: attempt to index field '?' (a nil value).
- ↑ Lua error in Module:Citation/CS1/Configuration at line 2088: attempt to index field '?' (a nil value).
- ↑ 7.0 7.1 Lua error in Module:Citation/CS1/Configuration at line 2088: attempt to index field '?' (a nil value).
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